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81.
Zora Jandrić Mohammad N. Rathor Sorivan Chhem-Kieth Joseph Adu-Gyamfi Leopold Mayr Christian Resch 《Journal of environmental science and health. Part. B》2013,48(12):1034-1042
Plant uptake of toxins and their translocation to edible plant parts are important processes in the transfer of contaminants into the food chain. Atropine, a highly toxic muscarine receptor antagonist produced by Solanacea species, is found in all plant tissues and can enter the soil and hence be available for uptake by crops. The absorption of atropine and/or its transformation products from soil by wheat (Triticum aestivum var Kronjet) and its distribution to shoots was investigated by growing wheat in soil spiked with unlabeled or 14C-labeled atropine. Radioactivity attributable to 14C-atropine and its transformation products was measurable in plants sampled at 15 d after sowing (DAS) and thereafter until the end of experiment. The highest accumulation of 14C-atropine and/or its transformation products by plants was detected in leaves (between 73 and 90% of the total accumulated) with lower amounts in stems, roots, and seeds (approximately 14%, 9%, and 3%, respectively). 14C-Atropine and/or its transformation products were detected in soil leachate at 30, 60, and 90 DAS and were strongly adsorbed to soil, with 60% of the applied dose adsorbed at 30 DAS, plateauing at 70% from 60 DAS. Unlabeled atropine was detected in shoots 30 DAS at a concentration of 3.9 ± 0.1 μg kg?1 (mean ± SD). The observed bioconcentration factor was 2.3 ± 0.04. The results suggest a potential risk of atropine toxicity to consumers. 相似文献
82.
Abstract The sorption and desorption characteristics of four herbicides (diuron, fluometuron, prometryn and pyrithiobac‐sodium) in three different cotton growing soils of Australia was investigated. Kinetics and equilibrium sorption and desorption isotherms were determined using the batch equilibrium technique. Sorption was rapid (> 80% in 2 h) and sorption equilibrium was achieved within a short period of time (ca 4 h) for all herbicides. Sorption isotherms of the four herbicides were described by Freundlich equation with an r2 value > 0.98. The herbicide sorption as measured by the distribution coefficient (Kd) values ranged from 3.24 to 5.71 L/kg for diuron, 0.44 to 1.13 L/kg for fluometuron, 1.78 to 6.04 L/kg for prometryn and 0.22 to 0.59 L/kg for pyrithiobac‐sodium. Sorption of herbicides was higher in the Moree soil than in Narrabri and Wee Waa soils. When the Kd values were normalised to organic carbon content of the soils (KoC), it suggested that the affinity of the herbicides to the organic carbon increased in the order: pyrithiobac‐sodium < fluometuron < prometryn < diuron. The desorption isotherms were also adequately described by the Freundlich equation. For desorption, all herbicides exhibited hysteresis and the hysteresis was stronger for highly sorbed herbicides (diuron and prometryn) than the weakly sorbed herbicides (fluometuron and pyrithiobac‐sodium). Hysteresis was also quantified as the percentage of sorbed herbicides which is not released during the desorption step ω = [nad / nde ‐1] x 100). Soil type and initial concentration had significant effect on ω. The effect of sorption and desorption properties of these four herbicides on the off‐site transport to contaminate surface and groundwater are also discussed in this paper. 相似文献
83.
In Hawaii, trace concentrations of pesticides used in the production of pineapple were found in the groundwater supplies of
Mililani Town in the Pearl Harbor Basin on the island of Oahu. Groundwater serves as the major source of drinking water and
residents pay for wellhead treatment of the contaminated water, via their monthly water bill. The agricultural chemical users
within the Pearl Harbor Basin do not include these wellhead treatment costs in their production costs. The agricultural industry
benefits from using pesticides but does not pay the entire societal cost of using these chemicals. In this study we evaluate
the specific financial cost of wellhead treatment, and not the economic value of groundwater. While wellhead treatment costs
could conceivably be shared by several parties, this study focuses on the financial impact of the pineapple industry alone.
This study factors annual wellhead treatment costs into annual pineapple production costs to measure the effect on annual
financial return from pineapple production. Wellhead treatment costs are calculated from the existing granulated activated
carbon (GAC) water treatment facility for Millilani Wells I and II. Pineapple production costs are estimated from previous
cost of production studies. The inclusion of wellhead treatment costs produces different production-cost results, depending
on the scale of analysis. At the local scale, the Mililani wellhead treatment costs can be factored into the production costs
of the pineapple fields, which were probably responsible for contamination of the Mililani Wells, without causing a deficit
in economic return. At the larger regional scale, however, the return from all of the pineapple grown in the Pearl Harbor
Basin can not sustain the cost of wellhead treatmentfor the entire water supply of the basin. Recommendations point to the
prevention of groundwater contamination as more cost-effective measure than wellhead treatment. 相似文献
84.
Robert C. Borden Philip B. Bedient 《Journal of the American Water Resources Association》1987,23(4):629-636
ABSTRACT: A three well injection-production test was performed at the United Creosoting Company (UCC) site in Conroe, Texas, to estimate the effective in situ retardation factors for adsorption and to evaluate the significance of biotransformation in limiting the transport of polycydic aromatics present in the shallow aquifer. The field test was also used as a model to determine if this type of testing would be feasible at other hazardous waste sites. During the test, chloride, a non-reactive tracer and two organic compounds, naphthalene and paradichlorobenzene (pDCB), were injected into a center well for 24 hours followed by clean ground water for six days. Ground water was continuously produced from two adjoining wells and monitored to observe the breakthrough of these compounds. Data from the test were analyzed by comparing the statistical moments of the chloride and organics distributions. Retardation factors for naphthalene and pDCB were estimated to be 1.03 and 0.97 by comparison of the statistical moments. A significant loss of naphthalene and pDCB was also observed during the three well test, apparently due to biotransformation. These results suggest that biotransformation is the major process limiting the transport of naphthalene and similar compounds at the UCC site. 相似文献
85.
G. William Page 《Journal of the American Water Resources Association》1988,24(4):847-854
ABSTRACT: Contamination of ground water supplies with volatile organic compounds is a new and significant problem. Municipalities and their community water systems are often the first to discover ground water contamination because of the monitoring programs they are required to carry out. When contamination exceeds standards, some action is required. The responses of Wisconsin municipalities to volatile organic compounds that exceed standards in their ground water sources is described. Actions to protect human health are prompt, but the survey results indicate plumes of contaminated ground water are usually not treated. They may continue to migrate and contaminate other private and public wells. 相似文献
86.
五氯酚对环境污染及居民健康影响研究 总被引:2,自引:0,他引:2
中国长期以来使用五氯酚纳盐杀灭亡血吸虫的中间宿主──—钉螺.为评价它对环境的污染及居民健康危害,1990-1993年在我省开展了五氯酚环境污染及对居民健康影响研究.在研究区采集环境样品(空气、水体、土壤及底泥、蔬菜、肉、蛋、鱼等)共173份;生物材料(人血、尿)共457份,分析五氯酚浓度.结果在明,在五氯酚使用区,环境中PCP浓度稍高于对照区,而生物材料尿、血中PCP浓度明显高于对照区.全血胆碱脂酶活性用药区明显低于对照区,统计学分析有显著差异(P<0.001),证实了长期低剂量使用可造成环境及生物蓄积. 相似文献
87.
88.
89.
本文对大巴山区农业生产中用化学药剂防治状况及存在的主要问题进行了分析研究。在此基础上,提出开展农药区划和区域性宏观调控,建立农药污染监测管理机制,进一步提高综合防治技术水平和专业化防治程度,加强防止污染微观技术的研究与推广控制策略和措施,以实现对化学药剂防治与农业生态环境保护。把农业环境保护工作纳入农业发展和国家农业环境保护的总体规划。 相似文献
90.
双流区域地下水污染现状及评价 总被引:1,自引:0,他引:1
本文在双流区域地下水污染调查基础之上,选用了主要反映工业生活污染的综合指标COD、BOD5和反映农业污染程度的NH3-N,NO3-N,NO2-N作为评价因子,研究了双流地下水污染现状,采用了综合指数法和点群分析法分类并评价了区域地下水污染对饮用水源地的影响程度。 相似文献